In this chapter the terms eac and scc are generally interchangeable. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. In addition, some intergranular fracture areas were also perceptible on. Damage due to hydrogen embrittlement and stress corrosion. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Both intergranular and transgranular stress corrosion cracking are. Sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. Material considerations when working with hydrogen 3. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of. Transgranular stress corrosion cracking tgscc is the same as igscc, but. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline. Although the scc was initiated by an intergranular mechanism, the crack propagation was transgranular. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries.
This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s. Wet hydrogen sulfide h2s cracking inspectioneering. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. The list of acronyms and abbreviations related to ssc sulfide stress cracking. This is, of course, a very complex question for a forum like this. Stress corrosion cracking odonnell consulting engineers. Occasionally, both types of cracking are observed in a failure. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. Sulfide stress cracking ssc is one of the detrimental types of corrosion which happens in sour environment. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism.
The threshold stresses to cause cracking are commonly below the yield stress of the material. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Sulphide stress cracking sscc has special importance in gas and oil industry, as the materials being processed there natural gas and crude oil often contain considerable amount of hydrogen sulphide. It addresses hydrogeninduced cracking of steel weldments, sensitization and subsequent intergranular corrosion of stainless steel weldments, sulfide stress cracking of pipeline steel weldments, microbiologically induced corrosion of weldments, and stress corrosion cracking of weldments.
Standard material requirements sulfide stress cracking. When the hinduced stress concentration exceeded the atomic binding force. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Stress relief cracking occurs only in metals that can precipitationharden during such elevatedtemperature exposure. Stress corrosion cracking can proceed in one of two ways. H2s partial pressure, 1 mpa and co2 partial pressure, 1 mpa. Nace tm01772016 laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments. Intergranular cracking is the cracking or fracture that occurs at and along the grain boundaries of a metal metals handbook, volume 11. Pdf sulfide stress corrosion cracking and hydrogen induced.
It is characterized by triple points, rockcandy or faceted appearance when the fracture is analyzed through sem metals handbook, volume 12. Intergranular corrosion igc can seriously weaken the bonding force between crystal grains and the mechanical strength of metals and alloys would be markedly. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods. Aug 14, 20 impact toughness of the casing decreased significantly and intergranular cracking occurred when specimens were maintained at a high stress level of 85%. An industry value that has been developed is nace mr01. Variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using te. Alloys which are commercially available and those which have modified metallurgical structures and. Intergranular cracking of oil field tubular components. Efc publication 17, 2nd edition, corrosion resistant alloys for oil and gas production. Mechanisms of stresscorrosion cracking asm international. Transgranular corrosion is also known as intragranular corrosion and transcrystalline corrosion.
Ian sutton, in plant design and operations second edition, 2017. Although the scc was initiated by an intergranular mechanism, the crack. Sulfide stress cracking an overview sciencedirect topics. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Lippold j and alexandrov b, phase transformations during welding and postweld heat treatment of a 12cr6. The effects of sulfide stress cracking on the mechanical. Is sulfide stress cracking an anodic or a cathodic process. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. In stress corrosion cracking, its first cousin, the corrosion process, generally pitting, must start to get the hydrogen generation started. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Standard material requirements sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. Hydrogen sulfide, being very toxic to people and wild life and polluting to the environment, is also very. Material damage due to hydrogen embrittlement and stress corrosion cracking can be classed as cases. Sulfide stress crackingresistant drill pipe addresses h2s.
Mechanical and metallurgical failure mechanisms flashcards. Pdf sulfide stress corrosion cracking and hydrogen. Propagation of stress corrosion cracks in pipeline. Sulfide stress cracking of highstrength steels is a problem in handling sour hydrogen sulfide containing crude oil or natural gas. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Sulfide stress cracking of pipelinecase history onepetro. Intergranular stress corrosion cracking an overview. Transgranular stress corrosion cracking tgscc cracks run through the individual grains. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel.
Prolonged exposure to sour gas can lead to hydrogen damage, sulfide stress cracking, andor stress corrosion cracking in ferrous alloys. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Ssc resistance in terms of rah2sraair and time to failure was found to decrease with increase of material strength. Cracking can result from creep damage, from fatigue cracking from sulfide stress cracking or hydrogen disbonding. Standard test method laboratory testing of metals for. This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures. Hydrogen induced cracking of subsea duplex stainless steel twi. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. H3 in the attached figures is the steam line break, since the lifting forces generated may be sufficient to elevate the top guide, possibly affecting lateral support of the. Transgranular cracking is a key characteristic of chloride induced stress corrosion cracking in austenitic stainless steels. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms.
In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. The embrittlement induced by ssc causes failure of steel at a stress level, which is significantly lower than its yield strength. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. However, the time required for crack initia tion is strongly dependent on a wide variety of pa rameters, such as surface finish. Stress corrosion cracking or season cracking occurs only in the simultaneous presence of a sufficiently high tensile stress and a specific corrosive environment. The effects of sulfide stress cracking on the mechanical properties. Sulfide stress cracking ssc also known as sour gas cracking sour gas. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Corrosionpedia what is sulfide stress cracking ssc. Sulfide stress cracking ssc resistance of casing steels with different alloying chemistries i. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf.
Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Thus, catastrophic failure can occur without significant deformation or obvious deterioration of the component. Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951. Laboratory testing of metals for resistance to sulfide. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Stress corrosion cracking odonnell consulting engineers, inc. Tib and mncrmo was evaluated using constant load tensile test and slow strain rate test in nacetm0177 environment. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular concern to the oil and gas industry 3.
Sulphide stress cracking is prevented by minimising the hardness and strength. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. Why is chloride stress corrosion cracking transgranular. Woollin p, postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels, proc conf stainless steel world 2005, kci publishing, paper no. By detailed metallurgical tests it was proven that the failure had been brought about by stress corrosion cracking. Intergranular stress corrosion cracking of welded steel twi. Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Vargas pm, wastberg s and woollin p, stress based design guidelines for hydrogen induced stress cracking hisc avoidance in duplex materials, proc conf omae 200979504. Intergranular stress corrosion cracking of core shrouds.
Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Transgranular stress corrosion cracking tgscc is the same as igscc, but the grain boundaries are not preferentially attacked 1, 2. Sulfide stress cracking behavior of a martensitic steel controlled by. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. Sulphide stress corrosion cracking sulphide stress cracking sscc has special importance in gas and oil industry, as the materials being processed there natural gas and crude oil often contain considerable amount of hydrogen sulphide. Sulfide stress cracking ssc vs hydrogen induced cracking. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Sulfide stress cracking is also environmentally produced so you have a delay until the sulfide environment causes hydrogen entry into the metal. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. Prior to the discovery of this new form of cracking, scc was thought to be a relatively wellunderstood, intergranular. H 2 s can cause sulfide stress cracking of stainless steels.
Reliability of dissimilar metal welds subjected to sulfide. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures.
Temperature is a significant environmental factor affecting cracking. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Sulfide stress cracking how is sulfide stress cracking. Oct 24, 20 sulfide stress cracking resistant drill pipe addresses h2s challenges.
Stresscorrosion cracking scc is a term used to describe. Stress corrosion cracking scc the impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. This form of cracking, which typically changes from transgranular 1 to intergranular 2 with increasing. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Effect of microstructure and crystallography on sulfide stress. Intergranular stress corrosion cracking igscc of bwr internal components has been identified as a technical issue of concern by both the nrc staff and the industry. Inter granular corrosion can be detected by ultrasonic and eddy current methods. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The required tensile stresses may be in the form of directly applied stresses or in the form of residual stresses, see an example of scc of an aircraft component. In recognition of the variation with temperature and with different materials this phenomenon is here called environmental cracking ec. Sulphide stress corrosion cracking sscc laboratory. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require.
These tests were carried out on specimens, which were pretreated under the following conditions for 168 hours. Ssc quickly diminishes performance of downhole tubulars. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. The presence of flaws that concentrate stress or crevices that alter. Sulfide stress cracking resistant drill pipe addresses h2s challenges. Cracking of dissimilar metal welds occurs in the ferritic cs or low alloy side of a weld between an austenitic 300ss or nialloy and a ferritic material operating at high tmeperature. Variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using tensile and impact tests. Hydrogen sulfide stress corrosion cracking in materials. For brasses the environment involved is usually one containing ammonia or closely related substances such as amines, but atmospheres containing between 0. Producing wet sour gas presents some of the toughest technical challenges in the oil and gas business. Intergranular cracks follow the grain boundaries in the metal. Sscc is a low temperature temperature where water is liquid effect of h2s in an aqueous environment and sulfidation is the term used for the. Sulfide stress cracking susceptibility tests were conducted as per nace tm 017796 method a, the tests were conducted at different applied loads 60%, 80%, and 110% of the yield strength values of the welded samples. A typical indication for this kind of damage is the branched cracks of fig.
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